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PHOSPHORESCENT PIGMENTS
INTRODUCTION:
.......Our Phosphorescent pigments are a
new type of long persistence phosphorescent pigment of alkaline earth aluminate
activated by rare earth ions. The main characteristic of this material is the
particular structure of its crystal with the strong capacity of
absorbing-storing-emitting light. After absorbing varieties of visible lights
(suitable for common light in room), it can glow for more than twelve hours in
the dark. The brightness and length of persistence time are more tens times
than those of the conventional phosphor of zinc sulfide. The material itself
has nontoxic and harmless and free from any radioactive additives. It has good
stability and weatherability. Excitation and emission can be repeated
indefinitely.
APPLICATION:
.......The new type of pigment is used
for many very different technical and artistic purposes due to its
characteristics. It can be used in manufacturing paint; ink; plastic; rubber
and films etc. It is completely safe for the application in consumer products
such as clothing; shoes; caps; toys; stationery goods; watch; switch;
novelties; fishing tools and sporting goods. It has good effects in the fields
of building; decoration; traffic vehicle; military installations; fire
emergency system. It is especially suitable for the production of long
afterglow safety products such as warning; mandatory and escape-route signs.
TECHNICAL SPECIFICATION:
Appearance:
Glowcolor:
Decay Time:
Density:
Particle Size:
Moisture:
Continuity: |
light yellow; light green; red;
blue; yellow; green
yellow-green; blue-green; red; blue; yellow; green
up to 12 hours after absorbing the light for 10 - 30 minutes
3.5+/-O. 1 g/cm3
10 - 65 um
0.5 %
the luminosity is over 5 years |
MSDS:
Our pigments are certified in a program of free from any radioactive
additives.
| Description |
Appearance |
Glowing color |
Model |
Average size (um) |
| Daytime |
Night |
| PL Series Pigments |
Purple |
Purple |
PLP-7 |
30-50 |
| Light-Yellow |
 |
 |
Yellow-Green |
PLO-6
PLO-7
PLO-8 |
B: 45-65
C: 20-40
D: 10-15
E: 5-10
F: 2-5 |
| Light-Green |
 |
 |
Blue-Green |
PLB-6
PLB-7 |
B: 45-65
C: 20-40
D: 10-15
E: 5-10 |
| S Series Pigments |
Yellow-Green |
Blue-Green |
LBG-101 |
25-45 |
| Yellow-Green |
Yellow-Green |
LG-101 |
25-45 |
| Light-green |
 |
 |
Blue-green |
SBG-8 |
B: 45-65
C: 20-40 |
| Light-white |
 |
 |
Blue |
SB-8 |
B: 45-65
C: 20-40 |
Light-White
Light-Yellow
Yellow-Green |
Yellow-Green |
S-2
S-3
S-4 |
2: 15-26
3: 45-60
4: 20-40 |
| R Series Pigments |
Red |
 |
 |
Red |
RR-7 |
20-50 |
| Orange |
 |
 |
Orange-red |
RO-7 |
20-50 |
| White |
Red |
REO-1 |
15-40 |
Characteristics:
| 1. |
PL series of photoluminescent pigment is made of alkaline
earth aluminate. With appearance of light yellow, its glowing color can be
yellow-green and blue-green, after absorbing visible light, especially those of
short waves beneath 450nm, PL series of pigment can glow for more than 20 hours
in the dark. |
| 2. |
Absorbing light speedily and emiting light in gay colors, R
series of photoluminescent pigment can be used not only as pigment in day, but
also with luminous effect in night. Its appearances are red, orange, yellow and
glowing colors are red, orange-red, orange-yellow. |
| 3. |
With good water resistance property and better stability
and strong capacity of absorbing short waves beneath 450nm, especially suitable
for water-base medium, S series of photoluminescent pigment can give out blue,
blue--green, green and yellow light. |
| 4. |
M series of photoluminescent pigment presents gay
appearance colors with blue, green, yellow and red. It can be used not only in
day but also with luminous effect in night. |
LUMI. LONG AFTERGLOW PHOTOLUMINESCENT
PIGMENT
- Introduction:
LUMI. long afterglow photoluminescent pigment (LM) is a new
type of long decay phosphor for alkaline earth aluminate activated by rare
earth ions. It has ten times brightness and glowing time than those of the
traditional phosphor of zinc sulfide. It could last emitting for the whole
night after low density light (200LX). The emission density could be upgraded
with lighting enhance and it also could be excited by the light of UV, the sun
fluorescent. The product itself is nontoxic and harmless and free from any
radioactive additives. It has good stability and weatherability. Excitation and
emission can be repeated, and its property at same time is almost no declined.
LM was granted a China patent in 1992 after over ten years of research. Now our
products have been exported to and distributed in quite a few countries and
regions such as USA, Japan, Korea, Canada, Singapore and etc.
- Application:
The new type of pigment is used for many very different
technical and artistic purposes due to its characteristics. It can be used in
manufacturing paint, ink, plastic, rubber and film etc. It is completely safe
for the application in consumer products such as clothing, shoes, caps, fields
of building, decorating, traffic vehicle, military installations, fire
emergency system. It is specially suitable for the production of long afterglow
safety products such as warning, mandatory and escape route signs.
- Comparison of LM with conventional phosphorescent pigments
| Name |
LM |
Conventional |
| Chemical
Identity |
Alkaline Earth
Aluminate |
ZnS:Cu |
| Body
Color |
Light Yellow-Green |
Yellow-Green |
| Av. Particle Size
(um) |
45-65 |
40-50 |
| Excitation
Energy(nm) |
200-450 |
200-450 |
| Emission Wave
Length (nm) |
520 |
530 |
| Afterglow
Brightness(1) (mcd/m2) |
340 |
16 |
| Afterglow
Extinction(2) (min) |
2000 |
About 200 |
| Excitation
Time(3)(min) |
10 |
10 |
| Light
Fastness |
> 1000
hours |
100hr diminish 65%
1000hr diminish to zero |
| Chemical
Stability |
Excellent |
Poor to Good |
| Specific
Gravity |
3.6g/cm3 |
4.1g/cm3 |
| Note: |
- Brightness after 10min, excitation with a D65 illuminant
for 10min at 1000LX.
- Time span necessary for afterglow brightness to diminish to
0.32mcd/M2.
- Time required for saturation with standard D6.5 illuminant
at 1000LX.
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- Features and Properties of LM
- Brightness and Emission Color
The pigment is exposed under direct ultra violet rays (UV) from the sun, black
lamps, halogen lamps, discharge lamps and other light sources which are rich in
UV light, it can emit the yellow-green light.
- Light Fastness
LM and a ZnS:Cu based phosphorescent pigment were tested for light fastness as
described below, and the results are shown in the following table.
Test samples were irradiated with a standard light source (300W Mercury Lamp)
for 1000hr, under the conditions of temperature=38-4OoC and
humidity--80%
Photoluminescent
Pigment |
Relative
Afterglow |
| Unexposed |
10hr |
100hr |
300hr |
1000hr |
| LM |
100 |
98 |
98 |
97 |
97 |
| ZnS:Cu |
100 |
86 |
35 |
0 |
0 |
- Afterglow Characteristics
It was excited with a D6.5 light source at 1000LX for 10
minutes. The emission is 340mcd/M2 at 10 min, 55mcd/m2 respectively. Its time
is over 2000 minutes. Lumi. is TEN TIMES BRIGHTER and has over ten times
afterglow of ZnS:Cu based pigment.
- Effect of Light Source on Afterglow
Brightness
LM's afterglow brightness increases with increase in light
Source intensity, whereas the classical phosphorescent pigments reach a plateau
around 300 Lux light intensity.
- Effect of Excitation Time on Afterglow
Brightness
LM shows a much higher capacity of absorbing and storing light
energy compared to classical phosphorescent pigment.
Application of Photoluminescent Pigment
In Paint, Ink and Plastic
LM may be used in all types of paint, powder coatings,
silk-screen ink, enamels, plastics and even porcelain. As the pigment has a
slight solubility in water, the only unsuitable are aqueous ones. For optimum
performance the following suggestions should be careful:
- Use a transparent solvent -vehicle with natural or alkaline
PH
- Do not grind the pigment, just stir. If possible use light
colored ceramic or glass lined vessels.
- Shelf life depends on the moisture content of the vehicle,
if moisture is present, shelf life is diminished. Although solvent based paints
do not contain moisture, some of them might absorb ambient moisture. Therefore
take precautions to minimize this from happening.
- To minimize settling, use a viscous vehicle or
anti-settling agents. Stir well prior to application.
- Apply a white base coat under the phosphorescent layer to
improve afterglow.
- Apply a clear overcoat to protect the pigment from humidity
and to improve gross.
- All additions should be free of heavy metal
compounds.
- Plan on using 20 to 60 percent pigment (by weight)
- Inks: Silk Screen &UV cured
- Viscosity of inks should be about 3000-5000 poise. During
printing viscosity should be adjusted by using a diluting agent based on
printing speed.
- Apply a white base coat under the phosphorescent layer to
improve afterglow.
- Minimum film thickness of the LM layer should be 100 um. In
order to achieve maximum afterglow, a film thickness of 130-150um is required.
For achieving this thickness two passes may be necessary.
- Ideal screen size would be 80-100 mesh. Larger screen
openings would give better results.
- To minimize settling, use a viscous vehicle and/or
anti-settling agents. Also stir well prior to printing.
- One kilogram of dry LM can cover 3.5 square meter
area.
- It is important to keep the entire system dry!
- LM is compatible with acrylic, polyester, epoxy, pvc,
polypropylene and polyethylene (HDPE, LDPE etc.) polymers.
- Material can be cast, dipped, coated, extruded or
molded.
- Preferably use master batches or compounds for
incorporating LM into plastics. As LM is a very hard substance and the
particles have a needle like shape, it is difficult to incorporate into plastic
resins directly.
- It is recommended to use an extruding temperature as low as
possible.
- Master batches containing LM must be fully dried up before
usage.
- Plan on using less than classical phosphorescent pigment
loadings.
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